青云英语翻译

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方案2。 3变动中的齐墩果酸的合成。试剂及条件:(一)2 - 碘酰基苯甲酸,甲苯,二甲基亚砜,RT,4小时;(二)1:ch2n2,乙醚,0°C至RT; 2:(S) - (A)-2 - (diphenylhydroxymethyl )吡咯烷,bh3Ásme2,四氢呋喃,RT,1小时;(三)二乙基乙二醇,nh2nh2,氢氧化钾,200°C,4小时;(四)brph3p + CH3,kotbu,四氢呋喃,RT,2小时;(五)LIL DMF,回流,过夜;(六)乙基草酰氯,三乙胺,DCM,0°C RT,4小时(G)碳酸氢钠(AQ),四氢呋喃,甲醇,1小时(H)相应的酸酐,甲苯,吡啶,回流,过夜;(i)若R

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方案 2。3 悼齐墩果酸的合成。试剂和条件: (a) 2 iodoxybenzoic 酸、 甲苯、 二甲基亚砜、 RT,4 小时 ;(b) 1:0 ° C 至 RT ; Et2O,CH2N22: (s)-(À)-2-吡咯烷 (diphenylhydroxymethyl)、 BH3ÁSMe2、 四氢呋喃、 RT,1 小时 ;(c) 二乙酯乙二醇、 NH2NH2、 KOH,200 ° C,4 小时 ;(c18 d) BrPh3P + 不,KOtBu,四氢呋喃、 RT,2 小时

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计划2.〃综合3-大茴香绿色甚至橘子oleanolic酸。
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